赵云辉,男,博士,副教授,硕士生导师,毕业于复旦大学化学系,现主要从事生物活性分子与功能材料的合成及应用研究。承担《药物合成》和《新药研发前沿》等课程的教学工作。曾获湖南科技大学“优秀班主任”、“教学优良榜”、“就业创业工作先进个人”等荣誉称号。参与国家自然科学基金项目多项,主持省部级课题4项和其它项目多项,指导国家级、省级大学生创新创业训练项目、大学生化学化工创新作品竞赛多项。近年来在《Anal. Chim. Acta》、《Org. Chem. Front.》、《Dyes and Pigments》、《Tetrahedron Lett.》、《Synlett》等国内外重要刊物上公开发表SCI论文20余篇,授权发明专利10余项。
联系方式:Email: zhao_yunhui@163.com
发表的主要论文:
[1]. Y.-H. Zhao,*Y. Yu, T. Guo, Z. Zhou, Z. Tang, L. Tian, Design, synthesis and applications of fluoride probe based on aromatization of isoquinolinium salts, Dyes and Pigments , 2020, Doi: https://doi.org/10.1016/j.dyepig.2020.108547.
[2]. T. Guo*; X.-N. Wei; M. Zhang; Y. Liu; L.-M. Zhu; Yun-Hui Zhao*; Catalyst and additive-free oxidative dual C-H sulfenylation of imidazoheterocycles with elemental sulfur using DMSO as solvent and oxidant, Chemical Communications , 2020, 56, 5751-5754.
[3]. Y.-H. Zhao,* Y. Yu, D. Hu, L. Zhao, W. Xie, Z. Zhou, Cascade oxidation /radical addition/ annulation of o -alkynylarylaldimine with indole/imidazopyridine: access to aromatic heterocycle-substituted isoquinolines, Asian J. Org. Chem. , 2020, 9, 953-960.
[4].Y.-H. Zhao*, Y. Luo, H. Wang, H. Wei, T. Guo, H. Tan, L. Yuan, X.-B. Zhang, A novel ratiometric and reversible fluorescence probe with a large Stokes shift for Cu2+ based on a new clamp-on unit. Anal. Chim. Acta 2019, https://doi.org/10.1016/j.aca.2019.03.029.
[5]. T. Guo,* X.-N. Wei, Y. Liu, P.-K. Zhang and Y.-H. Zhao*, Oxidative dual C–H selenation of imidazoheterocycles with ethersor alkanes using selenium powder via a radical pathway, Org. Chem. Front., 2019, DOI: 10.1039/C9QO00198K
[6]. Y.-H. Zhao, Y. Luo, H. Wang, T. Guo*, H. Zhou, H. Tan, Z. Zhou*, Y. Long, Z. Tang, A New Fluorescent Probe Based on Aggregation Induced Emission for Selective and Quantitative Determination of Copper(II) and its Further Application to Cysteine Detection, Chemistryselect, 2018, 3, 1521-1526.
[7]. Y.-H. Zhao*, Y. Luo, Y. Zhu, H. Wang, H. Zhou, H. Tan, Z. Zhou*, Y.-C. Ma*, W. Xie, Z. Tang, Synthesis of potential anticancer 1-(1H-Indol-3-yl)-isoquinolines via AgNO3-mediated tandem reactions of 2-alkynylbenzaldehyde azines and indoles, Synlett , 2018, 29,773-778.
[8]. T. Guo*, X.-N. Wei, H.-Y. Wang, Y.-L. Zhu, Y.-H. Zhao*, Y.-C. Ma*, Copper-catalyzed chalcogenation ofimidazoheterocycles with sulfur/selenium powderand coumarinyltriflates, Org. Biomol. Chem. 2017, 15, 9455-9464.
[9]. Y.-H. Zhao, Y. Li, M. Luo, Z. Tang, K. Deng, AgNO3-Mediated Cyclization/N-N Bond Cleavage Reaction for the Synthesis of 3-Aryl Isoquinolines, Synlett, 2016, 27, 2597-2600;
[10]. Y.-H. Zhao, Y. Li, Y. Long, Z. Zhou, Z. Tang, K. Deng, S. Zhang, Highly selective fluorescence turn-on determination of fluoride ions via chromogenic aggregation of a silyloxy-functionalized salicylaldehyde azine, Tetrahedron Lett., 2017, 58, 1351-1355.
授权发明专利:
[1] 赵云辉,李余波,一种吡唑并异喹啉化合物及其合成方法,ZL201510900073.0.
[2] 赵云辉,周智华,刘立华,谢文林,唐子龙, 一种基于聚集诱导发光的温敏荧
光材料及其制备方法和应用, ZL201611112262.2.
[3] 赵云辉,李余波,周智华,唐子龙,龙云飞, 一种基于聚集诱导发光的氟离子检测探针及其制备方法和应用, ZL201610969539.7.
[4] 赵云辉,周智华,刘立华,谢文林,唐子龙, 一种基于四苯乙烯的荧光化合物及其制备方法和应用, ZL201611269867.2.